WebF2, of a pre-reactive complex of oxirane and F2 were observed with a Balle-Flygare microwave spectrometer. Chemical reaction between the components was avoided by use of a fast-mixing nozzle. WebThe high resolution Fourier transform technique has been extensively applied in the centimeter range. In the past few years great progress have been made in observing molecular complexes. Most instruments operate between 2 and 26 GHz. So, very light interesting molecular species cannot be observed.
Original configuration of the Balle-Flygare spectrometer. LO, Local ...
WebWillis H. Flygare was Professor of Chemistry at University of Illinois, Urbana-Champaign (1961-1981). His research interests included light scattering and … WebRotational spectra have been observed for several 13C/18O isotopic species of the pseudolinear acetylene–carbon monoxide dimer using the pulsed, Fourier transform Balle/Flygare microwave spectrometer. A quadrature detection system has been incorporated in the data processing system to avoid folding of the spectrum onto itself in … how does johnny depp look now
John H. Holloway
WebThe pulsed nozzle Fourier transform microwave (PNFTMW) spectrometer was developed by Balle and Flygare [A new method for observing the rotational spectra of weak molecular complexes: KrHCl. J ... WebRotational spectra are reported for several isotopic species of the OC–and H3N–HCN–HF heterotrimers, detected with a pulsed nozzle, Fourier transform, Balle/Flygare microwave spectrometer.Rotational constants for the main isotopic species of the OC trimer are a B 0 of 615.574 MHz and D J of 251 Hz, and for H3N, a symmetric top, a B 0 of 1067.161 MHz … WebThe microwave rotational spectra of four isotopic species of a linear dimer NCCN⋅⋅⋅HF formed between cyanogen and hydrogen fluoride have been observed and analyzed to give vibrational gound state rotational constants B0, centrifugal distortion constants DJ, the 14N‐nuclear quadrupole coupling constants χ(1) and χ(2), and the H, 19F nuclear … how does johnson describe imperialism